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The development of phosphine-free "tethered" ruthenium(II) catalysts for the asymmetric reduction of ketones and imines
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G. Nedden, Hans, Zanotti-Gerosa, Antonio and Wills, Martin (2016) The development of phosphine-free "tethered" ruthenium(II) catalysts for the asymmetric reduction of ketones and imines. The Chemical Record, 16 (6). pp. 2623-2643. doi:10.1002/tcr.201600084 ISSN 1527-8999.
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Official URL: http://dx.doi.org/10.1002/tcr.201600084
Abstract
In this account, we describe the design, synthesis and applications of tethered versions of the Ru(II)/N‐tosyl‐1,2‐diphenylethylene‐1,2‐diamine (TsDPEN) class of catalyst that are commonly used for asymmetric transfer hydrogenation and asymmetric hydrogenation of ketones and imines. The review covers key aspects of the reaction mechanisms and examples of applications, including industrial applications to pharmaceutically important target molecules. In addition, closely related catalysts based on Rh(III) and Ir(III) are also described.
Item Type: | Journal Article | ||||||||||||
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Subjects: | Q Science > QD Chemistry | ||||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||||
Library of Congress Subject Headings (LCSH): | Catalysts, Ruthenium, Ketones, Imines | ||||||||||||
Journal or Publication Title: | The Chemical Record | ||||||||||||
Publisher: | Wiley-Blackwell Publishing Ltd. | ||||||||||||
ISSN: | 1527-8999 | ||||||||||||
Official Date: | 7 December 2016 | ||||||||||||
Dates: |
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Volume: | 16 | ||||||||||||
Number: | 6 | ||||||||||||
Page Range: | pp. 2623-2643 | ||||||||||||
DOI: | 10.1002/tcr.201600084 | ||||||||||||
Status: | Peer Reviewed | ||||||||||||
Publication Status: | Published | ||||||||||||
Access rights to Published version: | Open Access (Creative Commons) | ||||||||||||
Description: | Special Issue: 15th Anniversary of Nobel Prize to Ryoji Noyori |
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Date of first compliant deposit: | 28 March 2018 | ||||||||||||
Date of first compliant Open Access: | 28 March 2018 | ||||||||||||
RIOXX Funder/Project Grant: |
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