Measurement of lateral charge propagation in polyaniline layers with the scanning electrochemical microscope
UNSPECIFIED (2003) Measurement of lateral charge propagation in polyaniline layers with the scanning electrochemical microscope. JOURNAL OF PHYSICAL CHEMISTRY B, 107 (2). pp. 407-410. ISSN 1520-6106Full text not available from this repository.
Official URL: http://dx.doi.org/10.1021/jp021623x
The local injection and lateral propagation of charge in ultrathin polyaniline (PAN) layers have been studied with the scanning electrochemical microscope (SECM). Monolayers of PAN were deposited on a glass substrate using the LB method and were chemically reduced using sodium dithionite. A microelectrode held close to the PAN layer was used to generate a flux of an oxidant, i.e., Fe(phen)(3)(3+) (phen = 1,10-phenanthroline) which diffused to the surface and locally oxidized the reduced PAN. By simulating the current-time transients, the kinetics of lateral charge propagation have been evaluated.
|Item Type:||Journal Item|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||JOURNAL OF PHYSICAL CHEMISTRY B|
|Publisher:||AMER CHEMICAL SOC|
|Date:||16 January 2003|
|Number of Pages:||4|
|Page Range:||pp. 407-410|
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