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Dynamic kinetic resolution-asymmetric transfer hydrogenation of 1-aryl-substituted cyclic ketones
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UNSPECIFIED (2002) Dynamic kinetic resolution-asymmetric transfer hydrogenation of 1-aryl-substituted cyclic ketones. TETRAHEDRON-ASYMMETRY, 13 (22). pp. 2485-2490. ISSN 0957-4166
Full text not available from this repository.Abstract
A range of 1-aryl-2-tetranols, and 1-phenyl-2-indanol, have been generated in high yield and enantiomeric excess from the corresponding racemic ketones, via a dynamic kinetic resolution-transfer hydrogenation process, using Ru(II)-TsDPEN in formic acid/triethylamine (5:2). This provides a potential entry to an asymmetric total synthesis of benzazepines such as Sch 39166. (C) 2002 Elsevier Science Ltd. All rights reserved.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | TETRAHEDRON-ASYMMETRY |
| Publisher: | PERGAMON-ELSEVIER SCIENCE LTD |
| ISSN: | 0957-4166 |
| Date: | 13 November 2002 |
| Volume: | 13 |
| Number: | 22 |
| Number of Pages: | 6 |
| Page Range: | pp. 2485-2490 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/10339 |
Data sourced from Thomson Reuters' Web of Knowledge
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