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An expanded MIL-53-type coordination polymer with a reactive pendant ligand
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Kunicki, Hannah, Chamberlain, Thomas W., Clarkson, Guy J., Kashtiban, Reza J., Hooper, Joseph E., Dawson, Daniel M., Ashbrook, Sharon E. and Walton, Richard I. (2018) An expanded MIL-53-type coordination polymer with a reactive pendant ligand. CrystEngComm, 20 (31). pp. 4355-4358. doi:10.1039/C8CE00891D ISSN 1466-8033.
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Official URL: https://doi.org/10.1039/C8CE00891D
Abstract
A coordination polymer with a structure isoreticular to MIL-53, but containing a divalent metal cation (Co2+ or Mg2+) and a coordinating 4-styrylpyridine-N-oxide ligand, crystallises under solvothermal conditions; the pendant ligand can be brominated, with evidence from powder X-ray diffraction, element mapping and 81Br solid-state NMR for this post-synthesis modification.
Item Type: | Journal Article | ||||||||||||||||||||||||
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Subjects: | Q Science > QD Chemistry | ||||||||||||||||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry Faculty of Science, Engineering and Medicine > Science > Physics |
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Library of Congress Subject Headings (LCSH): | Coordination polymers, Organometallic compounds, Ligands | ||||||||||||||||||||||||
Journal or Publication Title: | CrystEngComm | ||||||||||||||||||||||||
Publisher: | Royal Society of Chemistry | ||||||||||||||||||||||||
ISSN: | 1466-8033 | ||||||||||||||||||||||||
Official Date: | 21 August 2018 | ||||||||||||||||||||||||
Dates: |
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Volume: | 20 | ||||||||||||||||||||||||
Number: | 31 | ||||||||||||||||||||||||
Page Range: | pp. 4355-4358 | ||||||||||||||||||||||||
DOI: | 10.1039/C8CE00891D | ||||||||||||||||||||||||
Status: | Peer Reviewed | ||||||||||||||||||||||||
Publication Status: | Published | ||||||||||||||||||||||||
Access rights to Published version: | Open Access (Creative Commons) | ||||||||||||||||||||||||
Date of first compliant deposit: | 3 August 2018 | ||||||||||||||||||||||||
Date of first compliant Open Access: | 3 August 2018 | ||||||||||||||||||||||||
RIOXX Funder/Project Grant: |
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