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Oxidative cross-coupling of boron and antimony nucleo-philes via palladium(I)
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Simpson, Quillon, Sinclair, Matthew J. G., Lupton, David W., Chaplin, Adrian B. and Hooper, Joel F. (2018) Oxidative cross-coupling of boron and antimony nucleo-philes via palladium(I). Organic Letters, 20 (18). pp. 5537-5540. doi:10.1021/acs.orglett.8b01989 ISSN 1523-7060.
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Official URL: https://doi.org/10.1021/acs.orglett.8b01989
Abstract
The use of an isolatable, monomeric Pd(I) complex as a catalyst for the oxidative cross-coupling of aryl- antimony and aryl-boron nucleophiles is reported. This reaction tolerates a wide variety of substrates, with >20:1 selectivity for cross-coupled products. This strategy offers a new approach to achieving the selective cross-coupling of nucleophiles.
Item Type: | Journal Article | ||||||||||||||||||
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Subjects: | Q Science > QD Chemistry | ||||||||||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||||||||||
Library of Congress Subject Headings (LCSH): | Nucleophilic reactions, Catalysts, Catalysis | ||||||||||||||||||
Journal or Publication Title: | Organic Letters | ||||||||||||||||||
Publisher: | American Chemical Society | ||||||||||||||||||
ISSN: | 1523-7060 | ||||||||||||||||||
Official Date: | 21 September 2018 | ||||||||||||||||||
Dates: |
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Volume: | 20 | ||||||||||||||||||
Number: | 18 | ||||||||||||||||||
Page Range: | pp. 5537-5540 | ||||||||||||||||||
DOI: | 10.1021/acs.orglett.8b01989 | ||||||||||||||||||
Status: | Peer Reviewed | ||||||||||||||||||
Publication Status: | Published | ||||||||||||||||||
Access rights to Published version: | Open Access (Creative Commons) | ||||||||||||||||||
Date of first compliant deposit: | 18 October 2018 | ||||||||||||||||||
Date of first compliant Open Access: | 18 October 2018 | ||||||||||||||||||
RIOXX Funder/Project Grant: |
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