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Poly(acryloyl hydrazide), a versatile scaffold for the preparation of functional polymers : synthesis and post-polymerisation modification
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Crisan, Daniel N., Creese, Oliver, Ball, Ranadeb, Brioso, Jose Luis, Martyn, Benjamin T., Montenegro, Javier and Fernandez-Trillo, Francisco (2017) Poly(acryloyl hydrazide), a versatile scaffold for the preparation of functional polymers : synthesis and post-polymerisation modification. Polymer Chemistry, 8 (31). pp. 4576-4584. doi:10.1039/c7py00535k ISSN 1759-9962.
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Official URL: http://dx.doi.org/10.1039/c7py00535k
Abstract
Here we present the synthesis and post-polymerisation modification of poly(acryloyl hydrazide), a versatile scaffold for the preparation of functional polymers: poly(acryloyl hydrazide) was prepared from commercially available starting materials in a three step synthesis on a large scale, in good yields and high purity. Our synthetic approach included the synthesis of a Boc-protected acryloyl hydrazide, the preparation of polymers via RAFT polymerisation and the deprotection of the corresponding Boc-protected poly(acryloyl hydrazide). Post-polymerisation modification of poly(acryloyl hydrazide) was then demonstrated using a range of conditions for both hydrophilic and hydrophobic aldehydes. These experiments demonstrate the potential of poly(acryloyl hydrazide) as a scaffold in the synthesis of functional polymers, in particular those applications where in situ screening of the activity of the functionalised polymers may be required (e.g. biological applications).
| Item Type: | Journal Article | ||||||||
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| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||
| SWORD Depositor: | Library Publications Router | ||||||||
| Journal or Publication Title: | Polymer Chemistry | ||||||||
| Publisher: | Royal Society of Chemistry (RSC) | ||||||||
| ISSN: | 1759-9962 | ||||||||
| Official Date: | 20 August 2017 | ||||||||
| Dates: |
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| Volume: | 8 | ||||||||
| Number: | 31 | ||||||||
| Page Range: | pp. 4576-4584 | ||||||||
| DOI: | 10.1039/c7py00535k | ||||||||
| Status: | Peer Reviewed | ||||||||
| Publication Status: | Published | ||||||||
| Access rights to Published version: | Open Access (Creative Commons) | ||||||||
| Related URLs: |
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