Effect of water on copper mediated living radical polymerization
UNSPECIFIED (2002) Effect of water on copper mediated living radical polymerization. In: 3rd International Symposium on Free-Radical Polymerization: Kinetics and Mechanism II Ciocco, LUCCA, ITALY, 2001. Published in: MACROMOLECULAR SYMPOSIA, 182 pp. 261-272.Full text not available from this repository.
The use of water as a solvent for copper mediated living radical polymerization has been further investigated. Optimal conditions for effective living radical polymerization using catalyst complexes based on CuBr and N-(n-alkyl)-2-pyridylmethanimine ligands were found, leading to well defined polymer structures. The effect of water on the rate of polymerization was studied, and it was found that competitive complexation of ligand and water occurs at copper in addition to an enhanced polymerization rate on increasing the polarity of the medium.
|Item Type:||Conference Item (UNSPECIFIED)|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||MACROMOLECULAR SYMPOSIA|
|Publisher:||WILEY-V C H VERLAG GMBH|
|Number of Pages:||12|
|Page Range:||pp. 261-272|
|Title of Event:||3rd International Symposium on Free-Radical Polymerization: Kinetics and Mechanism II Ciocco|
|Location of Event:||LUCCA, ITALY|
|Date(s) of Event:||2001|
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