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The structure of the Pd(110)(2 x 1)-CO surface

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UNSPECIFIED (2002) The structure of the Pd(110)(2 x 1)-CO surface. Surface Science, 511 (1-3). pp. 34-42. ISSN 0039-6028.

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Abstract

The structure of the Pd(1 1 0)(2 x 1)-CO ordered adsorption phase has been determined by scanned-energy mode photoelectron diffraction. The CO molecules are adsorbed close to short-bridge sites with alternating tilts along the close-packed <110> surface rows. This local geometry is consistent with that found in previous theoretical total energy calculations and an earlier X-ray photoelectron diffraction study, but is in direct contradiction to the results of an earlier quantitative low energy electron diffraction investigation. While the best-fit model structure involves some twist of the CO molecules out of the <1 0 0> mirror planes of the surface creating a surface phase of p1g1 symmetry, the more symmetric p2mg falls within the estimated limits of precision of the analysis. (C) 2002 Elsevier Science B.V. All rights reserved.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Q Science > QC Physics
Journal or Publication Title: Surface Science
Publisher: ELSEVIER SCIENCE BV
ISSN: 0039-6028
Official Date: 10 June 2002
Dates:
DateEvent
10 June 2002UNSPECIFIED
Volume: 511
Number: 1-3
Number of Pages: 9
Page Range: pp. 34-42
Publication Status: Published

Data sourced from Thomson Reuters' Web of Knowledge

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