Preparation of fluorinated methacrylic copolymers by copper mediated living radical polymerization
UNSPECIFIED. (2002) Preparation of fluorinated methacrylic copolymers by copper mediated living radical polymerization. TETRAHEDRON, 58 (20). pp. 4053-4059. ISSN 0040-4020Full text not available from this repository.
The synthesis of fluorinated macroinitiators and macromonomers for copper mediated living radical polymerization is reported. In a first approach, various fluorinated telomers showing one or two hydroxy groups are transformed into initiators via esterification. The resultant macroinitiators are used for the polymerization of methyl methacrylate (MMA) to give well-defined block copolymers. In a second approach, the same telomers were transformed into methacrylic monomers and subsequently polymerised using living radical polymerization. In both cases, the final products of polymerization show molecular weights close to expected, assuming living polymerization, with polydispersities of approximately 1.1-1.2. (C) 2002 Elsevier Science Ltd. All lights reserved.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||TETRAHEDRON|
|Publisher:||PERGAMON-ELSEVIER SCIENCE LTD|
|Date:||13 May 2002|
|Number of Pages:||7|
|Page Range:||pp. 4053-4059|
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