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2-D soft ferromagnet based on [W-V(CN)(8)](3-) and Cu-II with a T-c of 34 K
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UNSPECIFIED. (2002) 2-D soft ferromagnet based on [W-V(CN)(8)](3-) and Cu-II with a T-c of 34 K. CHEMICAL COMMUNICATIONS (10). pp. 1138-1139. ISSN 1359-7345
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Official URL: http://dx.doi.org/10.1039/b202810g
Abstract
Self-assembly of [Cu(tetren)](2+) (tetren = tetraethylenepentamine) and [W(CN)(8)](3-) in acidic aqueous solution yields the double-layered square grid cyanide-bridged polymer of {(tetrenH(5))(0.8)Cu-4(II)[W-v(CN)(8)](4).7.2H(2)O}(n) with Cu(II) centres of square pyramidal geometry coordinatively saturated solely by CN bridges supplied by five [W(CN)(8)](3-) ions; it exhibits soft ferromagnetic behaviour with an ordering temperature T-c of 34 K.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | CHEMICAL COMMUNICATIONS |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 1359-7345 |
| Date: | 2002 |
| Number: | 10 |
| Number of Pages: | 2 |
| Page Range: | pp. 1138-1139 |
| Identification Number: | 10.1039/b202810g |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/10965 |
Data sourced from Thomson Reuters' Web of Knowledge
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