Triple helicates and planar dimers arising from silver(I) coordination to directly linked bis-pyridylimine ligands
UNSPECIFIED. (2002) Triple helicates and planar dimers arising from silver(I) coordination to directly linked bis-pyridylimine ligands. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (8). pp. 1635-1641. ISSN 1472-7773Full text not available from this repository.
Official URL: http://dx.doi.org/10.1039/b110137b
Silver(I) coordination is investigated for three ligands of the pyridine-azine class, in which two pyridylimine binding units are linked directly through the imine nitrogen atoms. H-1 NMR, X-ray analysis and ESI mass spectrometry indicate the presence of a range of metallo-supramolecular architectures in solution for all three ligands. X-Ray analysis confirms the solid state structures for a dinuclear triple helicate containing five-coordinate silver centres and a dinuclear dimer in which the silver ions are three-coordinate with long range stabilising interactions to trifluoromethanesulfonate counter-ions. A tetranuclear grid-like array is also implied as a component of the solution library. The five-coordinate silver(I) ions in the triple helicate result in a hetero-ligand system with two ligands oriented in a head-to-tail fashion. This is distinct from the triple helicates formed with octahedral metals such as an iron(II) triple helicate also crystallographically characterised herein.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS|
|Publisher:||ROYAL SOC CHEMISTRY|
|Number of Pages:||7|
|Page Range:||pp. 1635-1641|
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