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Absolute configuration and electronic state properties of light-switch complex [Ru(phen)(2)dppz](2+) deduced from oriented circular dichroism in a lamellar liquid crystal host

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UNSPECIFIED (2002) Absolute configuration and electronic state properties of light-switch complex [Ru(phen)(2)dppz](2+) deduced from oriented circular dichroism in a lamellar liquid crystal host. CHEMICAL PHYSICS LETTERS, 354 (1-2). pp. 44-50. ISSN 0009-2614.

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Abstract

Circular dichroism (CD) of enantiomers of [Ru(phen)(2)dppz](2+) oriented in a octanoate-decanol-water lamellar liquid crystal has been measured parallel to the orientation axis. where the sample does not exhibit linear dichroism (LD). At an inclined incidence, the emerging LD shows that the chromophores have an along-chain orientation in the liquid crystal. The changes in the CD spectrum compared to an isotropic sample, in conjunction with CD calculations, allow us to assess the absolute configuration of the enantiomers and assign the CD bands to specific electronic transitions. (C) 2002 Elsevier Science B.V. All rights reserved.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Q Science > QC Physics
Journal or Publication Title: CHEMICAL PHYSICS LETTERS
Publisher: ELSEVIER SCIENCE BV
ISSN: 0009-2614
Official Date: 5 March 2002
Dates:
DateEvent
5 March 2002UNSPECIFIED
Volume: 354
Number: 1-2
Number of Pages: 7
Page Range: pp. 44-50
Publication Status: Published
RIOXX Funder/Project Grant:
Project/Grant IDRIOXX Funder NameFunder ID
UNSPECIFIEDEngineering and Physical Sciences Research Councilhttp://dx.doi.org/10.13039/501100000266

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