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Synthesis of 2,5-dihydrofurans via alkylidene carbene insertion reactions
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UNSPECIFIED. (2002) Synthesis of 2,5-dihydrofurans via alkylidene carbene insertion reactions. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 (7). pp. 965-981. ISSN 1472-7781
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Official URL: http://dx.doi.org/10.1039/b111097g
Abstract
The insertion reaction of alkylidene carbenes is demonstrated to be an effective method for the synthesis of 2,5-dihydrofuran ring systems. The best results have been obtained on substrates containing electron-withdrawing substituents, which appear less prone to the competing rearrangement reaction. This insight has led to the development of a new method for the synthesis of the core structure of the squalestatin-zaragozic acid natural products.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 1472-7781 |
| Date: | 2002 |
| Number: | 7 |
| Number of Pages: | 17 |
| Page Range: | pp. 965-981 |
| Identification Number: | 10.1039/b111097g |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/11130 |
Data sourced from Thomson Reuters' Web of Knowledge
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