UNSPECIFIED. (2002) Doubly cyclopalladated pyridazines: chiral liquid crystals. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 645 (1-2). pp. 246-255. ISSN 0022-328X

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Abstract

The mono and dicyclopalladation of new mesogenic pyridazines and subsequent reaction with beta-diketones yields some novel metallomesogens. The monometallated derivatives have a flat central core. In contrast. the dimetallated derivatives have a sterically induced twist in the molecule that renders them chiral. Smectic A phases are typically exhibited by both the derivatives with transition temperatures in the region of 100-300 degreesC. (C) 2002 Elsevier Science B.V. All rights reserved.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Journal or Publication Title:	JOURNAL OF ORGANOMETALLIC CHEMISTRY
Publisher:	ELSEVIER SCIENCE SA
ISSN:	0022-328X
Date:	15 February 2002
Volume:	645
Number:	1-2
Number of Pages:	10
Page Range:	pp. 246-255
Publication Status:	Published
URI:	http://wrap.warwick.ac.uk/id/eprint/11133

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