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Doubly cyclopalladated pyridazines: chiral liquid crystals

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UNSPECIFIED (2002) Doubly cyclopalladated pyridazines: chiral liquid crystals. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 645 (1-2). pp. 246-255.

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Abstract

The mono and dicyclopalladation of new mesogenic pyridazines and subsequent reaction with beta-diketones yields some novel metallomesogens. The monometallated derivatives have a flat central core. In contrast. the dimetallated derivatives have a sterically induced twist in the molecule that renders them chiral. Smectic A phases are typically exhibited by both the derivatives with transition temperatures in the region of 100-300 degreesC. (C) 2002 Elsevier Science B.V. All rights reserved.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Journal or Publication Title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
Publisher: ELSEVIER SCIENCE SA
ISSN: 0022-328X
Official Date: 15 February 2002
Dates:
DateEvent
15 February 2002UNSPECIFIED
Volume: 645
Number: 1-2
Number of Pages: 10
Page Range: pp. 246-255
Publication Status: Published

Data sourced from Thomson Reuters' Web of Knowledge

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