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Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3
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Huddart, Benjamin M., Brambleby, Jamie, Lancaster, Tom, Goddard, Paul A., Xiao, Fan, Blundell, Stephen J., Pratt, Francis L., Macchi, Piero, Scatena, Rebecca, Barton, Alyssa M. and Manson, Jamie L. (2019) Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3. Physical Chemistry Chemical Physics, 21 (3). 1014-1018 . doi:10.1039/C8CP07160H ISSN 1463-9076.
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Official URL: https://doi.org/10.1039/C8CP07160H
Abstract
The quasi-one-dimensional molecule-based Heisenberg antiferromagnet Cu(NO3)2(pyz)3 has an intrachain coupling J = 13.7(1) K ( H = J Σi Si·Si+1) and exhibits a state of long-range magnetic order below TN = 0.105(1) K. The ratio of interchain to intrachain coupling is estimated to be |J'/J|= 3.3×10-3, demonstrating a high degree of isolation for the Cu chains.
| Item Type: | Journal Article | ||||||||||||
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| Divisions: | Faculty of Science, Engineering and Medicine > Science > Physics | ||||||||||||
| Journal or Publication Title: | Physical Chemistry Chemical Physics | ||||||||||||
| Publisher: | Royal Society of Chemistry | ||||||||||||
| ISSN: | 1463-9076 | ||||||||||||
| Official Date: | 2019 | ||||||||||||
| Dates: |
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| Volume: | 21 | ||||||||||||
| Number: | 3 | ||||||||||||
| Page Range: | 1014-1018 | ||||||||||||
| DOI: | 10.1039/C8CP07160H | ||||||||||||
| Status: | Peer Reviewed | ||||||||||||
| Publication Status: | Published | ||||||||||||
| Access rights to Published version: | Restricted or Subscription Access | ||||||||||||
| Date of first compliant deposit: | 10 December 2018 | ||||||||||||
| Date of first compliant Open Access: | 30 May 2019 | ||||||||||||
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