The Library
The role of symmetric functionalisation on photoisomerisation of a UV commercial chemical
Tools
Tools
Tools
Woolley, Jack Matthew, Peters, Jack S., Turner, Matthew A. P., Clarkson, Guy J., Horbury, Michael D. and Stavros, Vasilios G. (2019) The role of symmetric functionalisation on photoisomerisation of a UV commercial chemical. Physical Chemistry Chemical Physics, 21 (26). pp. 14350-14356. doi:10.1039/C8CP06536E ISSN 1463-9076. [ 🗎 Public]. [ (🔓): Yes ].
|
PDF
WRAP-role-symmetric-funtionalisation-photoisomerisation-UV-commercial-chemical-Stavros-2019.pdf - Published Version - Requires a PDF viewer. Available under License Creative Commons Attribution. Download (2438Kb) | Preview |
|
![[img]](http://wrap.warwick.ac.uk/style/images/fileicons/application_pdf.png) |
PDF
WRAP-role-symmetric-funtionalisation-photoisomerisation-chemical-Woolley-2018.pdf - Accepted Version Embargoed item. Restricted access to Repository staff only - Requires a PDF viewer. Download (980Kb) |
Official URL: https://doi.org/10.1039/C8CP06536E
Abstract
Photoisomerisation has been shown to be an efficient excited-state relaxation mechanism for a variety of nature-based and artificial-based molecular systems. Here we report on the excited-state relaxation dynamics and consequent photostability of a symmetrically functionalised cinnamate by transient electronic absorption spectroscopy, along with complementary computational and steady-state spectroscopy methods. The findings are then discussed in comparison to 2-ethylhexyl-E-4-methoxycinnamate, a structurally related ‘off the shelf’ chemical filter present in commercial sunscreens with a similar absorption profile. The present study allows for a like-for-like comparison beween 2-ethylhexyl-E-4-methoxycinnamate and the functionalised cinnamate, driven by the need to enhance solar protection across both the UVA and UVB regions of the electromagnetic spectrum.
| Item Type: | Journal Article | |||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | |||||||||||||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry Faculty of Science, Engineering and Medicine > Science > Physics |
|||||||||||||||
| Library of Congress Subject Headings (LCSH): | Photoisomerization, Ultraviolet radiation | |||||||||||||||
| Journal or Publication Title: | Physical Chemistry Chemical Physics | |||||||||||||||
| Publisher: | Royal Society of Chemistry | |||||||||||||||
| ISSN: | 1463-9076 | |||||||||||||||
| Official Date: | 14 July 2019 | |||||||||||||||
| Dates: |
|
|||||||||||||||
| Volume: | 21 | |||||||||||||||
| Number: | 26 | |||||||||||||||
| Page Range: | pp. 14350-14356 | |||||||||||||||
| DOI: | 10.1039/C8CP06536E | |||||||||||||||
| Status: | Peer Reviewed | |||||||||||||||
| Publication Status: | Published | |||||||||||||||
| Access rights to Published version: | Open Access (Creative Commons) | |||||||||||||||
| Date of first compliant deposit: | 18 December 2018 | |||||||||||||||
| Date of first compliant Open Access: | 10 April 2019 | |||||||||||||||
| Funder: | ||||||||||||||||
| RIOXX Funder/Project Grant: |
|
|||||||||||||||
| Related URLs: |
Request changes or add full text files to a record
Repository staff actions (login required)
 |
View Item |
Downloads
Downloads per month over past year
