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Problems and solutions for alkene polymerisation catalysts incorporating Schiff-bases; migratory insertion and radical mechanisms of catalyst deactivation
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UNSPECIFIED (2002) Problems and solutions for alkene polymerisation catalysts incorporating Schiff-bases; migratory insertion and radical mechanisms of catalyst deactivation. CHEMICAL COMMUNICATIONS (4). pp. 352-353. ISSN 1359-7345
Full text not available from this repository.Abstract
Steric blocking of an intramolecular 1,2-migratory insertion reaction of a zirconium salicylaldiminato complex leads to a long-lived catalyst for ethene polymerisation, but promotes a new radical catalyst decomposition mechanism in certain instances; kinetic and thermodynamic parameters for both pathways have been established.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | CHEMICAL COMMUNICATIONS |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 1359-7345 |
| Date: | 2002 |
| Number: | 4 |
| Number of Pages: | 2 |
| Page Range: | pp. 352-353 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/11254 |
Data sourced from Thomson Reuters' Web of Knowledge
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