Skip to content Skip to navigation
University of Warwick
  • Study
  • |
  • Research
  • |
  • Business
  • |
  • Alumni
  • |
  • News
  • |
  • About

University of Warwick
Publications service & WRAP

Highlight your research

  • WRAP
    • Home
    • Search WRAP
    • Browse by Warwick Author
    • Browse WRAP by Year
    • Browse WRAP by Subject
    • Browse WRAP by Department
    • Browse WRAP by Funder
    • Browse Theses by Department
  • Publications Service
    • Home
    • Search Publications Service
    • Browse by Warwick Author
    • Browse Publications service by Year
    • Browse Publications service by Subject
    • Browse Publications service by Department
    • Browse Publications service by Funder
  • Help & Advice
University of Warwick

The Library

  • Login
  • Admin

Petroleomic depth profiling of Staten Island salt marsh soil : 2ω detection FTICR MS offers a new solution for the analysis of environmental contaminants

Tools
- Tools
+ Tools

Thomas, Mary J., Collinge, Louise, Witt, Matthias, Palacio Lozano, Diana Catalina, Vane, Christopher H., Moss-Hayes, Vicky and Barrow, Mark P. (2019) Petroleomic depth profiling of Staten Island salt marsh soil : 2ω detection FTICR MS offers a new solution for the analysis of environmental contaminants. Science of The Total Environment, 662 . pp. 852-862. doi:10.1016/j.scitotenv.2019.01.228

[img]
Preview
PDF
WRAP-petroleomic-depth-profiling-Staten-Island-salt-marsh-soil-Barrow-2019.pdf - Accepted Version - Requires a PDF viewer.
Available under License Creative Commons Attribution Non-commercial No Derivatives 4.0.

Download (1989Kb) | Preview
Official URL: http://dx.doi.org/10.1016/j.scitotenv.2019.01.228

Request Changes to record.

Abstract

Staten Island is located in one of the most densely populated regions of the US: the New York/New Jersey Estuary. Marine and industrial oil spills are commonplace in the area, causing the waterways and adjacent marshes to become polluted with a range of petroleum-related contaminants. Using Rock-Eval pyrolysis, the hydrocarbon impact on a salt marsh was assessed at regular intervals down to 90 cm, with several key sampling depths of interest identified for further analysis. Ultrahigh resolution data are obtained by direct infusion (DI) atmospheric pressure photoionization (APPI) on a 12 T solariX Fourier transform ion cyclotron resonance mass spectrometer (FTICR MS) allowing trends in the compositional profile with depth to be observed, such as changes in the relative hydrocarbon intensity and the relative contributions from oxygen- and sulfur-containing groups. These trends may correlate with the timing of major oil spills and leaks of petroleum and other industrial chemicals into the waterways. The use of gas chromatography (GC) coupled to a 7 T solariX 2XR FTICR MS equipped with an atmospheric pressure chemical ionization (APCI) ion source offers retention time resolved and extensive compositional information for the complex environmental samples complementary to that obtained by DI-APPI. The compositional profile observed using GC-APCI FTICR MS includes contributions from phosphorous-containing groups, which may be indicative of contamination from other anthropogenic sources.

Item Type: Journal Article
Subjects: T Technology > TD Environmental technology. Sanitary engineering
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Soil -- Pollution -- Staten Island (New York, N.Y.), Salt marshes, Oil spills -- New Jersey
Journal or Publication Title: Science of The Total Environment
Publisher: Elsevier Science BV
ISSN: 0048-9697
Official Date: 20 April 2019
Dates:
DateEvent
20 April 2019Published
22 January 2019Available
21 January 2019Accepted
Volume: 662
Page Range: pp. 852-862
DOI: 10.1016/j.scitotenv.2019.01.228
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
RIOXX Funder/Project Grant:
Project/Grant IDRIOXX Funder NameFunder ID
EP/L015307/1[EPSRC] Engineering and Physical Sciences Research Councilhttp://dx.doi.org/10.13039/501100000266
275910721Newton Fundhttp://dx.doi.org/10.13039/100010897
FP44842-039-2015Departamento Administrativo de Ciencia, Tecnología e Innovaciónhttp://dx.doi.org/10.13039/100007637

Request changes or add full text files to a record

Repository staff actions (login required)

View Item View Item

Downloads

Downloads per month over past year

View more statistics

twitter

Email us: wrap@warwick.ac.uk
Contact Details
About Us