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On the relationship between the radiative rate constant and the fluorescence intensity in organic fluorophores

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UNSPECIFIED (2001) On the relationship between the radiative rate constant and the fluorescence intensity in organic fluorophores. CHEMICAL PHYSICS LETTERS, 350 (5-6). pp. 509-514. ISSN 0009-2614

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Abstract

In this Letter we explore the relationship between the radiative constant, k(r), and the lineshape of an emission spectrum for fluorescent organic molecules, in particular tryptophan, We make a number of judicious approximations to the expression given by Strickler and Berg in conjunction with the log-normal function for the lineshape. Our result is a closed form expression for k(r) in terms of the inverse maximum wavelength lambda(max)(-1) which compares well with recent experimental findings for tryptophan residues in proteins. (C) 2001 Elsevier Science B.V. All rights reserved.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Q Science > QC Physics
Journal or Publication Title: CHEMICAL PHYSICS LETTERS
Publisher: ELSEVIER SCIENCE BV
ISSN: 0009-2614
Date: 28 December 2001
Volume: 350
Number: 5-6
Number of Pages: 6
Page Range: pp. 509-514
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/11367

Data sourced from Thomson Reuters' Web of Knowledge

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