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Regiospecific high yield reductive coupling of diynes to give a luminescent rhodium complex
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UNSPECIFIED (2001) Regiospecific high yield reductive coupling of diynes to give a luminescent rhodium complex. CHEMICAL COMMUNICATIONS (24). pp. 2626-2627. ISSN 1359-7345
Full text not available from this repository.Abstract
Reaction of 2 equivalents of 1,4-bis(p-tolylethynyl)buta-1,3-diyne with [(PMe3)(4)Rh(-C equivalent to CSiMe3)] gives the unusual, highly luminescent mer, cis-[tris(trimethylphosphine)trimethylsilylethynyl-2,5-bis(p-tolylethynyl)-3,4-bis(p-tolyl)rhodacyclopenta-2,4-diene] 5 in quantitative yield which has been fully characterised by H-1 and P-31{H-1} NMR, IR, UV-VIS and luminescence spectroscopies, elemental analysis and single crystal X-ray diffraction.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | CHEMICAL COMMUNICATIONS |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 1359-7345 |
| Date: | 21 December 2001 |
| Number: | 24 |
| Number of Pages: | 2 |
| Page Range: | pp. 2626-2627 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/11378 |
Data sourced from Thomson Reuters' Web of Knowledge
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