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Investigation of rheological properties and conformation of cassava starch in zinc chloride solution
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Chen, Xiaodong, Liu, Peng, Shang, Xiaoqin, Xie, Fengwei, Jiang, Huihua and Wang, Jie (2017) Investigation of rheological properties and conformation of cassava starch in zinc chloride solution. Starch - Stärke, 69 (9-10). 1600384. doi:10.1002/star.201600384 ISSN 0038-9056.
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Official URL: http://dx.doi.org/10.1002/star.201600384
Abstract
Zinc chloride aqueous solution is a non‐derivatizing solvent for starch, and can be used as a media for homogeneous starch modification. Here, the rheological properties of starch in ZnCl2 aqueous solution under different conditions are considered. Specifically, a large number (120) of viscosity–shear‐rate curves for starch–ZnCl2 solutions with different starch contents, ZnCl2 concentrations, and temperatures were obtained and modeled using a master curve method. In particular, the power‐law index (n) from the modeling could accurately classify the starch molecules in ZnCl2 aqueous solutions into an insoluble state, a dilute state, a semi‐dilute state, and a sticky state, reflecting the different degrees of chain interactions in the solution. In particular, the sticky state would be mostly likely be controlled by the zinc–starch complex, which made the rheological behavior entirely different from that at low ZnCl2 concentrations. The knowledge obtained from this study can be used to guide the homogeneous modification of starch and the fabrication of starch‐based materials using green solvents such as aqueous ZnCl2 with desired properties.
| Item Type: | Journal Article | ||||||||||||||||||||||||
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| Subjects: | S Agriculture > SB Plant culture T Technology > TP Chemical technology |
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| Divisions: | Faculty of Science, Engineering and Medicine > Engineering > WMG (Formerly the Warwick Manufacturing Group) | ||||||||||||||||||||||||
| Library of Congress Subject Headings (LCSH): | Starch -- Research, Cassava, Zinc chloride, Starch crops | ||||||||||||||||||||||||
| Journal or Publication Title: | Starch - Stärke | ||||||||||||||||||||||||
| Publisher: | Wiley-Blackwell Publishing Ltd. | ||||||||||||||||||||||||
| ISSN: | 0038-9056 | ||||||||||||||||||||||||
| Official Date: | September 2017 | ||||||||||||||||||||||||
| Dates: |
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| Volume: | 69 | ||||||||||||||||||||||||
| Number: | 9-10 | ||||||||||||||||||||||||
| Article Number: | 1600384 | ||||||||||||||||||||||||
| DOI: | 10.1002/star.201600384 | ||||||||||||||||||||||||
| Status: | Peer Reviewed | ||||||||||||||||||||||||
| Publication Status: | Published | ||||||||||||||||||||||||
| Reuse Statement (publisher, data, author rights): | This is the peer reviewed version of the following article: Chen, X. , Liu, P. , Shang, X. , Xie, F. , Jiang, H. and Wang, J. (2017), Investigation of rheological properties and conformation of cassava starch in zinc chloride solution. Starch ‐ Stärke, 69: 1600384. doi:10.1002/star.201600384, which has been published in final form at https://doi.org/10.1002/star.201600384. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | ||||||||||||||||||||||||
| Access rights to Published version: | Restricted or Subscription Access | ||||||||||||||||||||||||
| Date of first compliant deposit: | 11 March 2019 | ||||||||||||||||||||||||
| Date of first compliant Open Access: | 11 March 2019 | ||||||||||||||||||||||||
| RIOXX Funder/Project Grant: |
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