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Non-dipole effects in photoelectron-monitored X-ray standing wave experiments: characterisation and calibration

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UNSPECIFIED (2001) Non-dipole effects in photoelectron-monitored X-ray standing wave experiments: characterisation and calibration. Surface Science, 494 (3). pp. 166-182. ISSN 0039-6028

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Abstract

The results are reported of a series of experiments designed to characterise and calibrate the role of non-dipolar (notably electric quadrupole-dipole interference) effects in the angular distribution of photoelectron emission on structural studies of surfaces using normal incidence X-ray standing wavefield absorption. The values of the resulting backward/forward asymmetry parameter (relative to the photon propagation direction) have been measured for Is emission at photon energies around 3 keV for first and second row elements from C to Cl. and are compared with recent theoretical determinations. The influence of additional non-dipole interference terms in the coherent X-ray standing wave has also been determined for the case of Al Ls emission and found to be weak. typically introducing systematic errors in atomic positions of only around 0.02-0.04 Angstrom. (C) 2001 Elsevier Science B.V. All rights reserved.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Q Science > QC Physics
Journal or Publication Title: Surface Science
Publisher: ELSEVIER SCIENCE BV
ISSN: 0039-6028
Date: 1 December 2001
Volume: 494
Number: 3
Number of Pages: 17
Page Range: pp. 166-182
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/11465

Data sourced from Thomson Reuters' Web of Knowledge

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