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Synthesis and applications to asymmetric catalysis of a series of mono- and bis(diazaphospholidine) ligands

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UNSPECIFIED (2001) Synthesis and applications to asymmetric catalysis of a series of mono- and bis(diazaphospholidine) ligands. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 (21). pp. 2840-2849. ISSN 1472-7781

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Abstract

The synthesis of a series of closely related mono- and bis(diazaphospholidine) ligands has been achieved using the condensation of a diamine with a bis(dimethylamino)arylphosphine. The resulting ligands have given excellent results in palladium-catalysed allylic substitution reactions to form C-C bonds (up to 89% ee) and C-N bonds (up to 78% ee).

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Journal or Publication Title: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
Publisher: ROYAL SOC CHEMISTRY
ISSN: 1472-7781
Date: 7 November 2001
Number: 21
Number of Pages: 10
Page Range: pp. 2840-2849
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/11572

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