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Conformational self-recognition as the origin of dewetting in bistable molecular surfaces
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UNSPECIFIED (2001) Conformational self-recognition as the origin of dewetting in bistable molecular surfaces. JOURNAL OF PHYSICAL CHEMISTRY B, 105 (44). pp. 10826-10830. doi:10.1021/jp011455t ISSN 1089-5647.
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Official URL: http://dx.doi.org/10.1021/jp011455t
Abstract
A thin film formed by an amphiphilic catenane is shown to exhibit bistable behavior. The film is grown by self-assembly from two different solutions onto a mica surface. Self-recognition of the solute molecules by the first monolayer of the adsorbed molecules drives the switch between two co-conformations, characterized by different polar character, which are nearly degenerate once deposited on the surface. The phenomenon takes the form of a wetting/dewetting transition and propagates the intramolecular change to the mesoscopic scale.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF PHYSICAL CHEMISTRY B | ||||
Publisher: | AMER CHEMICAL SOC | ||||
ISSN: | 1089-5647 | ||||
Official Date: | 8 November 2001 | ||||
Dates: |
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Volume: | 105 | ||||
Number: | 44 | ||||
Number of Pages: | 5 | ||||
Page Range: | pp. 10826-10830 | ||||
DOI: | 10.1021/jp011455t | ||||
Publication Status: | Published |
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