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Conformational self-recognition as the origin of dewetting in bistable molecular surfaces
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UNSPECIFIED. (2001) Conformational self-recognition as the origin of dewetting in bistable molecular surfaces. JOURNAL OF PHYSICAL CHEMISTRY B, 105 (44). pp. 10826-10830. ISSN 1089-5647
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Official URL: http://dx.doi.org/10.1021/jp011455t
Abstract
A thin film formed by an amphiphilic catenane is shown to exhibit bistable behavior. The film is grown by self-assembly from two different solutions onto a mica surface. Self-recognition of the solute molecules by the first monolayer of the adsorbed molecules drives the switch between two co-conformations, characterized by different polar character, which are nearly degenerate once deposited on the surface. The phenomenon takes the form of a wetting/dewetting transition and propagates the intramolecular change to the mesoscopic scale.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF PHYSICAL CHEMISTRY B |
| Publisher: | AMER CHEMICAL SOC |
| ISSN: | 1089-5647 |
| Date: | 8 November 2001 |
| Volume: | 105 |
| Number: | 44 |
| Number of Pages: | 5 |
| Page Range: | pp. 10826-10830 |
| Identification Number: | 10.1021/jp011455t |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/11573 |
Data sourced from Thomson Reuters' Web of Knowledge
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