Arz, Marius I., Annibale, Vincent T., Kelly, Nicole L., Hanna, John V. and Manners, Ian (2019) Ring-opening polymerization of cyclic phosphonates : access to inorganic polymers with a PV–O main chain. Journal of the American Chemical Society, 141 (7). pp. 2894-2899. doi:10.1021/jacs.8b13435 ISSN 0002-7863.

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Abstract

We describe a new class of inorganic polymeric materials featuring a main chain consisting of PV–O bonds and aryl side groups, which was obtained with >70 repeat units by ring-opening polymerization of cyclic phosphonates. This monomer–polymer system was found to be dynamic in solution enabling selective depolymerization under dilute conditions, which can be tuned by varying the substituents. The polymers show high thermal stability to weight loss and can be easily fabricated into self-standing thin films. Structural characterizations of the cyclic 6- and 12-membered ring precursors are also described.

Item Type:	Journal Article
Divisions:	Faculty of Science, Engineering and Medicine > Science > Chemistry Faculty of Science, Engineering and Medicine > Science > Physics
Journal or Publication Title:	Journal of the American Chemical Society
Publisher:	American Chemical Society
ISSN:	0002-7863
Official Date:	20 February 2019
Dates:	Date Event 20 February 2019 Published 6 February 2019 Available 6 February 2019 Accepted
Volume:	141
Number:	7
Page Range:	pp. 2894-2899
DOI:	10.1021/jacs.8b13435
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Open Access Version:	Other

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