
The Library
Ring-opening polymerization of cyclic phosphonates : access to inorganic polymers with a PV–O main chain
Tools
Arz, Marius I., Annibale, Vincent T., Kelly, Nicole L., Hanna, John V. and Manners, Ian (2019) Ring-opening polymerization of cyclic phosphonates : access to inorganic polymers with a PV–O main chain. Journal of the American Chemical Society, 141 (7). pp. 2894-2899. doi:10.1021/jacs.8b13435 ISSN 0002-7863.
![]() |
PDF
WRAP-supporting-2019.pdf - Supplemental Material Embargoed item. Restricted access to Repository staff only - Requires a PDF viewer. Download (4Mb) |
Official URL: http://dx.doi.org/10.1021/jacs.8b13435
Abstract
We describe a new class of inorganic polymeric materials featuring a main chain consisting of PV–O bonds and aryl side groups, which was obtained with >70 repeat units by ring-opening polymerization of cyclic phosphonates. This monomer–polymer system was found to be dynamic in solution enabling selective depolymerization under dilute conditions, which can be tuned by varying the substituents. The polymers show high thermal stability to weight loss and can be easily fabricated into self-standing thin films. Structural characterizations of the cyclic 6- and 12-membered ring precursors are also described.
Item Type: | Journal Article | ||||||||
---|---|---|---|---|---|---|---|---|---|
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry Faculty of Science, Engineering and Medicine > Science > Physics |
||||||||
Journal or Publication Title: | Journal of the American Chemical Society | ||||||||
Publisher: | American Chemical Society | ||||||||
ISSN: | 0002-7863 | ||||||||
Official Date: | 20 February 2019 | ||||||||
Dates: |
|
||||||||
Volume: | 141 | ||||||||
Number: | 7 | ||||||||
Page Range: | pp. 2894-2899 | ||||||||
DOI: | 10.1021/jacs.8b13435 | ||||||||
Status: | Peer Reviewed | ||||||||
Publication Status: | Published | ||||||||
Access rights to Published version: | Restricted or Subscription Access | ||||||||
Open Access Version: |
Request changes or add full text files to a record
Repository staff actions (login required)
![]() |
View Item |