Investigation of some starting protocols for BDF (FIRM) in electrochemical digital simulation
UNSPECIFIED (2001) Investigation of some starting protocols for BDF (FIRM) in electrochemical digital simulation. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 512 (1-2). pp. 119-123. ISSN 0022-0728Full text not available from this repository.
Starting procedures for the backward differentiation formula (BDF) method have been investigated for the simulation of a chronopotentiometric or chronoamperometric experiment. How to start a simulation becomes especially important if the second (spatial) derivative of concentration is approximated by a fourth-order difference formula. The method of Kimble and White (KW) has been adapted to provide high-accuracy starting values. A comparison with other starting procedures is made. Surprisingly, the simple BDF start with a time correction, as used by Feldberg and co-workers, although not as accurate as the KW start, is the most efficient method. Its efficiency (when using the higher-order spatial second derivative approximations) is shown to be almost the same as for the extrapolation technique which, as a one-step (in time) method, does not depend on a starting strategy. (C) 2001 Elsevier Science B.V. All rights reserved.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||JOURNAL OF ELECTROANALYTICAL CHEMISTRY|
|Publisher:||ELSEVIER SCIENCE SA|
|Date:||5 October 2001|
|Number of Pages:||5|
|Page Range:||pp. 119-123|
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