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Data for Rhodium(III) complexes featuring coordinated CF3 appendages
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Emerson-King, Jack, Prokes, Ivan and Chaplin, Adrian B. (2019) Data for Rhodium(III) complexes featuring coordinated CF3 appendages. [Dataset]
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WRAPdata 115060.zip - Accepted Version Available under License Creative Commons Attribution 4.0. Download (316Mb) |
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115060 README.txt - Accepted Version Available under License Creative Commons Attribution 4.0. Download (400b) |
Official URL: http://wrap.warwick.ac.uk/116255
Abstract
The synthesis and characterisation of a homologous series of rhodium 2,2′‐biphenyl complexes featuring intramolecular dative bonding of the nominally inert and weakly coordinating trifluoromethyl group are described. Presence of these interactions is evidenced in the solid state using X‐ray diffraction, with Rh−F contacts of 2.36–2.45 Å, and in solution using NMR spectroscopy, through hindered C−CF3 bond rotation and the presence of time‐averaged 1JRhF and 2JPF coupling.
Item Type: | Dataset | |||||||||||||||
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Subjects: | Q Science > QD Chemistry | |||||||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | |||||||||||||||
Type of Data: | High resolution mass spectrometry data. Microanalytical reports. NMR spectroscopy data; subdivided by instrument and experiment | |||||||||||||||
Library of Congress Subject Headings (LCSH): | Rhodium compounds, Biphenyl compounds | |||||||||||||||
Publisher: | University of Warwick, Department of Chemistry | |||||||||||||||
Official Date: | 15 April 2019 | |||||||||||||||
Dates: |
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Status: | Not Peer Reviewed | |||||||||||||||
Publication Status: | Published | |||||||||||||||
Media of Output (format): | File, .pdf .docx .txt | |||||||||||||||
Access rights to Published version: | Open Access (Creative Commons) | |||||||||||||||
Description: | Rhodium(III) Complexes Featuring Coordinated CF3 Appendages. The primary analytical data is organised by new rhodium complex. Alphanumeric codes of the form JEK#_### are lab book. references. |
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Date of first compliant deposit: | 15 April 2019 | |||||||||||||||
Date of first compliant Open Access: | 15 April 2019 | |||||||||||||||
RIOXX Funder/Project Grant: |
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