UNSPECIFIED (2001) Back bonding without sigma-bonding: a unique pi-complex of dinitrogen with uranium. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 635 (1-2 Sp. Iss. SI). pp. 69-74. ISSN 0022-328X

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Abstract

The synthesis, molecular structure, spectroscopic properties and bonding in a complex of dinitrogen with trivalent uranium are described. The molecule has a side-on U-N-2-U Core which is supported by U -->N-2 pi donation with no significant N-2 --> U bonding. Steric compression between the spectator triamidoamine ligands prevents the uranium atoms from approaching the N-2 ligand at the optimum distance for overlap, and thus the N-N distance is not displaced significantly from that in gaseous dinitrogen. (C) 2001 Elsevier Science BN. All rights reserved.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Journal or Publication Title:	JOURNAL OF ORGANOMETALLIC CHEMISTRY
Publisher:	ELSEVIER SCIENCE SA
ISSN:	0022-328X
Date:	15 October 2001
Volume:	635
Number:	1-2 Sp. Iss. SI
Number of Pages:	6
Page Range:	pp. 69-74
Publication Status:	Published
URI:	http://wrap.warwick.ac.uk/id/eprint/11638

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