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Ion-exchange resin as a new tool for characterisation of coordination compounds and MOFs by NMR spectroscopy
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Serra, Osvaldo A., Borges da Silva Galaço, Ayla R., Thiago de Oliveira, Kleber , Donatoni, Maria Carolina and Walton, Richard I. (2019) Ion-exchange resin as a new tool for characterisation of coordination compounds and MOFs by NMR spectroscopy. Chemical Communications, 55 (56). pp. 8106-8109. doi:10.1039/C9CC03721G ISSN 1359-7345.
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Official URL: https://doi.org/10.1039/C9CC03721G
Abstract
1H and 13C NMR spectroscopy is used to investigate the organic constituents of metal complexes, MOFs and coordination compounds synthesised under solvothermal and precipitation conditions. The elucidation of the ligands in paramagnetic compounds bearing Cu2+(d9), Gd3+ (f7), Eu3+ (f6), Fe3+(d5), ions after treatment with a cationic exchange resin is possible. We prove the efficiency of two post-synthesis linker modifications on diamagnetic IRMOF-3 Zn2+ (d10) with ethyl isocyanate and benzyl bromide.
Item Type: | Journal Article | ||||||||||||
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Subjects: | Q Science > QD Chemistry | ||||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||||
Library of Congress Subject Headings (LCSH): | Inorganic ion exchange materials, Ion exchange resins, Nuclear magnetic resonance spectroscopy | ||||||||||||
Journal or Publication Title: | Chemical Communications | ||||||||||||
Publisher: | Royal Society of Chemistry | ||||||||||||
ISSN: | 1359-7345 | ||||||||||||
Official Date: | 18 July 2019 | ||||||||||||
Dates: |
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Volume: | 55 | ||||||||||||
Number: | 56 | ||||||||||||
Page Range: | pp. 8106-8109 | ||||||||||||
DOI: | 10.1039/C9CC03721G | ||||||||||||
Status: | Peer Reviewed | ||||||||||||
Publication Status: | Published | ||||||||||||
Access rights to Published version: | Restricted or Subscription Access | ||||||||||||
Date of first compliant deposit: | 19 June 2019 | ||||||||||||
Date of first compliant Open Access: | 17 June 2020 | ||||||||||||
RIOXX Funder/Project Grant: |
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