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Experimental and theoretical studies on the oxidative addition of palladium(0) to beta-chlorovinamidinium salts
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UNSPECIFIED (2001) Experimental and theoretical studies on the oxidative addition of palladium(0) to beta-chlorovinamidinium salts. TETRAHEDRON, 57 (24). pp. 5061-5066. ISSN 0040-4020.
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Abstract
Boronic acids, esters and borinic anhydrides are partners in Suzuki-Miyaura cross-coupling reactions with a variety of beta -chlorovinamidinium salts to give the desired beta -arylvinamidinium salts in up to 88% yield. Reduction is a competing reaction pathway. DFT calculations on the intermediate palladium complex reveal that the Pd-C interaction is predominantly of a-symmetry and the metal based LUMO is mainly d(z2) in character. (C) 2001 Elsevier Science Ltd. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | TETRAHEDRON | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0040-4020 | ||||
Official Date: | 11 June 2001 | ||||
Dates: |
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Volume: | 57 | ||||
Number: | 24 | ||||
Number of Pages: | 6 | ||||
Page Range: | pp. 5061-5066 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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