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Experimental and theoretical studies on the oxidative addition of palladium(0) to beta-chlorovinamidinium salts
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UNSPECIFIED (2001) Experimental and theoretical studies on the oxidative addition of palladium(0) to beta-chlorovinamidinium salts. TETRAHEDRON, 57 (24). pp. 5061-5066. ISSN 0040-4020
Full text not available from this repository.Abstract
Boronic acids, esters and borinic anhydrides are partners in Suzuki-Miyaura cross-coupling reactions with a variety of beta -chlorovinamidinium salts to give the desired beta -arylvinamidinium salts in up to 88% yield. Reduction is a competing reaction pathway. DFT calculations on the intermediate palladium complex reveal that the Pd-C interaction is predominantly of a-symmetry and the metal based LUMO is mainly d(z2) in character. (C) 2001 Elsevier Science Ltd. All rights reserved.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | TETRAHEDRON |
| Publisher: | PERGAMON-ELSEVIER SCIENCE LTD |
| ISSN: | 0040-4020 |
| Date: | 11 June 2001 |
| Volume: | 57 |
| Number: | 24 |
| Number of Pages: | 6 |
| Page Range: | pp. 5061-5066 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/12079 |
Data sourced from Thomson Reuters' Web of Knowledge
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