Experimental and theoretical studies on the oxidative addition of palladium(0) to beta-chlorovinamidinium salts
UNSPECIFIED (2001) Experimental and theoretical studies on the oxidative addition of palladium(0) to beta-chlorovinamidinium salts. TETRAHEDRON, 57 (24). pp. 5061-5066. ISSN 0040-4020Full text not available from this repository.
Boronic acids, esters and borinic anhydrides are partners in Suzuki-Miyaura cross-coupling reactions with a variety of beta -chlorovinamidinium salts to give the desired beta -arylvinamidinium salts in up to 88% yield. Reduction is a competing reaction pathway. DFT calculations on the intermediate palladium complex reveal that the Pd-C interaction is predominantly of a-symmetry and the metal based LUMO is mainly d(z2) in character. (C) 2001 Elsevier Science Ltd. All rights reserved.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||TETRAHEDRON|
|Publisher:||PERGAMON-ELSEVIER SCIENCE LTD|
|Date:||11 June 2001|
|Number of Pages:||6|
|Page Range:||pp. 5061-5066|
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