UNSPECIFIED (2001) Optical and electroemission properties of thin films of supermolecular anthracene-based rotaxanes. In: 10th International Conference on Solid Films and Surfaces (ICSFS-10), JUL 09-13, 2000, PRINCETON UNIV, PRINCETON, NEW JERSEY.

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Abstract

Rotaxanes are a new class of functional materials. They consist of mechanically interlocked supermolecular systems where a central linear thread passes through the cavity of a macrocyclic ring. The ring is constrained within the two extremities of the thread by two bulky stoppers. In this work, we report on spectroscopic characterisation of an anthracene-based novel rotaxane (EPAR-Me) and on the electroemission (EL) from a basic rotaxane component (ANTPEP). An OLED has been prepared using the anthracene-based thread (ANTPEP) of the EPAR-Me rotaxane in polycarbonate matrices. Spectroscopic measurements are reported, supporting excimer-like EL and field dependent electroexcimer for the ANTPEP thin film. Tentative assignment of emitting species of EPAR-Me are also discussed. (C) 2001 Elsevier Science B.V. All rights reserved.

Item Type:	Conference Item (UNSPECIFIED)
Subjects:	Q Science > QD Chemistry T Technology > TA Engineering (General). Civil engineering (General) Q Science > QC Physics
Journal or Publication Title:	Surface Science
Publisher:	ELSEVIER SCIENCE BV
ISSN:	0169-4332
Date:	15 May 2001
Volume:	175
Number of Pages:	5
Page Range:	pp. 369-373
Publication Status:	Published
Title of Event:	10th International Conference on Solid Films and Surfaces (ICSFS-10)
Location of Event:	PRINCETON UNIV, PRINCETON, NEW JERSEY
Date(s) of Event:	JUL 09-13, 2000
URI:	http://wrap.warwick.ac.uk/id/eprint/12117

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