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Synthesis and characterization of the novel bridged ligand 5,8-dimethyl-1,5,8,12-tetraazabicyclo[10.3.2]heptadecane and its complexes with iron(II) and manganese(II) ions
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UNSPECIFIED (2001) Synthesis and characterization of the novel bridged ligand 5,8-dimethyl-1,5,8,12-tetraazabicyclo[10.3.2]heptadecane and its complexes with iron(II) and manganese(II) ions. JOURNAL OF COORDINATION CHEMISTRY, 52 (4). pp. 317-331. ISSN 0095-8972
Full text not available from this repository.Abstract
The bridged tetradentate ligand 5,8-dimethyl-1,5,8,12-tetraazabicyclo[10.3.2]heptadecane (L-1) has been prepared, and its complexes with manganese(II) and iron(II) synthesized and characterized. The crystal structure of MnL1(NCS)(2) has been determined: the Mn is octahedral with cis-NCS ligands, and the asymmetric unit contains two independent molecules differing slightly in the Mn--N--C angles. The oxidation of the complexes by hydrogen peroxide is also discussed.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF COORDINATION CHEMISTRY |
| Publisher: | GORDON BREACH PUBLISHING, TAYLOR & FRANCIS GROUP |
| ISSN: | 0095-8972 |
| Date: | 2001 |
| Volume: | 52 |
| Number: | 4 |
| Number of Pages: | 15 |
| Page Range: | pp. 317-331 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/12237 |
Data sourced from Thomson Reuters' Web of Knowledge
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