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Si-29 T-1 relaxation in alkali silicate glasses: a method for detecting glass-in-glass phase separation

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UNSPECIFIED (2001) Si-29 T-1 relaxation in alkali silicate glasses: a method for detecting glass-in-glass phase separation. JOURNAL OF NON-CRYSTALLINE SOLIDS, 281 (1-3). pp. 108-116. ISSN 0022-3093

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Abstract

High resolution nuclear magnetic resonance (NMR) has been used to measure relaxation times, T-1, in alkali silicate glasses. Two-component relaxation was observed in lithium silicate glasses. In glasses close to the sodium disilicate composition, the relaxation was one component but, with decreasing sodium content, this becomes two component. In heat-treated sodium silicate glasses two components appear to grow from the single component and the extent of growth depends upon the heal-treatment temperature and time. The results for all systems are explained in terms of phase separation and all insight into the Q " distribution is also presented. (C) 2001 Elsevier Science B.V. All rights reserved.

Item Type: Journal Article
Subjects: T Technology > TP Chemical technology
T Technology > TA Engineering (General). Civil engineering (General)
Journal or Publication Title: JOURNAL OF NON-CRYSTALLINE SOLIDS
Publisher: ELSEVIER SCIENCE BV
ISSN: 0022-3093
Date: March 2001
Volume: 281
Number: 1-3
Number of Pages: 9
Page Range: pp. 108-116
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/12336

Data sourced from Thomson Reuters' Web of Knowledge

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