UNSPECIFIED (2001) 5-exo atom transfer cyclisation onto alkynes mediated by copper(I) complexes. TETRAHEDRON LETTERS, 42 (10). pp. 1999-2001. ISSN 0040-4039

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Abstract

Multidentate amine derived copper(I) halide complexes mediate the atom transfer radical cyclisation of 1-halo-N-propargylacetamides. While cyclisation of trichloro- and dichloroacetamide derivatives leads to alpha,beta -unsaturated gamma -lactams containing the gem-dihalide functional group, monohaloacetamides give rise to either cyclised atom transfer or reduction products depending upon the solvent and catalyst used. (C) 2001 Elsevier Science Ltd. All rights reserved.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Journal or Publication Title:	TETRAHEDRON LETTERS
Publisher:	PERGAMON-ELSEVIER SCIENCE LTD
ISSN:	0040-4039
Date:	4 March 2001
Volume:	42
Number:	10
Number of Pages:	3
Page Range:	pp. 1999-2001
Publication Status:	Published
URI:	http://wrap.warwick.ac.uk/id/eprint/12349

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