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Rearrangement of unactivated N-alkyl-O-benzoyl hydroxamic acid derivatives with phosphazene bases

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UNSPECIFIED (2001) Rearrangement of unactivated N-alkyl-O-benzoyl hydroxamic acid derivatives with phosphazene bases. TETRAHEDRON LETTERS, 42 (10). pp. 2007-2009. ISSN 0040-4039

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Abstract

The phosphazene super bases BTPP 5, P-2-'Bu 6, and P-4-'Bu 7 mediate the rearrangement of unactivated N-alkyl-O-benzoyl hydroxamic acid derivatives 8, 11a-f, 13 and 16 to give 2-benzoyloxy amides 9, 12a-f, 14 and 17. The rate of reaction was found to be dependant upon the steric nature of the N-alkyl substituent. (C) 2001 Elsevier Science Ltd. All rights reserved.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Journal or Publication Title: TETRAHEDRON LETTERS
Publisher: PERGAMON-ELSEVIER SCIENCE LTD
ISSN: 0040-4039
Date: 4 March 2001
Volume: 42
Number: 10
Number of Pages: 3
Page Range: pp. 2007-2009
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/12351

Data sourced from Thomson Reuters' Web of Knowledge

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