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Photoemission study of pristine and potassium intercalated benzylic amide [2]catenane films
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UNSPECIFIED (2001) Photoemission study of pristine and potassium intercalated benzylic amide [2]catenane films. Surface Science, 474 (1-3). pp. 37-46. ISSN 0039-6028
Full text not available from this repository.Abstract
In this paper we report a photoelectron spectroscopy XPS and UPS) study of films of a benzylic amide [2]catenane on Au(1 1 1). We show that this molecule retains its molecular integrity during sublimation and that it chemisorbs on the metal surface. Potassium intercalation modifies the electronic structure of the films. We have observed a reduction of its amide functions and a modification of the charge density of the aromatic rings. The creation of polaron-like states in the gap of the neutral catenane and a decrease in the catenane work function of 0.8 eV have been demonstrated. (C) 2001 Elsevier Science B.V. All rights reserved.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry Q Science > QC Physics |
| Journal or Publication Title: | Surface Science |
| Publisher: | ELSEVIER SCIENCE BV |
| ISSN: | 0039-6028 |
| Date: | 1 March 2001 |
| Volume: | 474 |
| Number: | 1-3 |
| Number of Pages: | 10 |
| Page Range: | pp. 37-46 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/12352 |
Data sourced from Thomson Reuters' Web of Knowledge
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