Photoemission study of pristine and potassium intercalated benzylic amide catenane films
UNSPECIFIED. (2001) Photoemission study of pristine and potassium intercalated benzylic amide catenane films. Surface Science, 474 (1-3). pp. 37-46. ISSN 0039-6028Full text not available from this repository.
In this paper we report a photoelectron spectroscopy XPS and UPS) study of films of a benzylic amide catenane on Au(1 1 1). We show that this molecule retains its molecular integrity during sublimation and that it chemisorbs on the metal surface. Potassium intercalation modifies the electronic structure of the films. We have observed a reduction of its amide functions and a modification of the charge density of the aromatic rings. The creation of polaron-like states in the gap of the neutral catenane and a decrease in the catenane work function of 0.8 eV have been demonstrated. (C) 2001 Elsevier Science B.V. All rights reserved.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry
Q Science > QC Physics
|Journal or Publication Title:||Surface Science|
|Publisher:||ELSEVIER SCIENCE BV|
|Date:||1 March 2001|
|Number of Pages:||10|
|Page Range:||pp. 37-46|
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