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Specific formation of (M-H)(-) ions from OH-group-containing molecules

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UNSPECIFIED (2001) Specific formation of (M-H)(-) ions from OH-group-containing molecules. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 205 (1-3 Sp. Iss. SI). pp. 119-135. ISSN 1387-3806

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Abstract

The formation of (M-H)(-) ions from OH-containing benzene derivatives, covering azobenzenes and phenols, has been investigated by resonant electron-capture mass spectrometry. A vibrational fine structure in the effective ion yield curves, at threshold energies for the formation of these ions through OH-bond cleavage, has been observed. This vibrational progression has been assigned to the nu (OH) stretching mode, It has been supposed that the formation of these ions occurs by a predissociation of the vibrationally excited ground state of the parent anion. (C) 2001 Elsevier Science B.V.

Item Type: Journal Article
Subjects: Q Science > QC Physics
Journal or Publication Title: INTERNATIONAL JOURNAL OF MASS SPECTROMETRY
Publisher: ELSEVIER SCIENCE BV
ISSN: 1387-3806
Date: 20 February 2001
Volume: 205
Number: 1-3 Sp. Iss. SI
Number of Pages: 17
Page Range: pp. 119-135
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/12428

Data sourced from Thomson Reuters' Web of Knowledge

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