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A hydrothermally stable Ytterbium metal-organic framework as a bifunctional solid-acid catalyst for glucose conversion
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Burnett, David L., Oozzeerally, Ryan, Pertiwi, Ralentri, Chamberlain, Thomas W., Cherkasov, Nikolay, Clarkson, Guy J., Krisnandi, Yuni, Degirmenci, Volkan and Walton, Richard I. (2019) A hydrothermally stable Ytterbium metal-organic framework as a bifunctional solid-acid catalyst for glucose conversion. Chemical Communications, 55 (76). pp. 11446-11449. doi:10.1039/C9CC05364F ISSN 1359-7345.
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WRAP-hydrothermally-stable-ytterbium-metal-organic-bifunctional-catalyst-Walton-2019.pdf - Published Version - Requires a PDF viewer. Available under License Creative Commons Attribution. Download (2466Kb) | Preview |
Official URL: http://doi.org/10.1039/C9CC05364F
Abstract
Yb6(BDC)7(OH)4(H2O)4 contains both bridging hydroxyls and metal-coordinated waters, possessing Brønsted and Lewis acid sites. The material crystallises from water at 200C. Using the solid as a heterogenous catalyst, glucose is converted into 5-hydroxymethylfurfural, via fructose, with a total selectivity of ~70 % after 24 hours at 140 C in water alone: the material is recyclable with no loss of crystallinity.
| Item Type: | Journal Article | ||||||||||||
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| Subjects: | Q Science > QD Chemistry T Technology > TP Chemical technology |
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| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry Faculty of Science, Engineering and Medicine > Engineering > Engineering |
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| Library of Congress Subject Headings (LCSH): | Glucose, Ytterbium , Heterogeneous catalysis , Biomass conversion | ||||||||||||
| Journal or Publication Title: | Chemical Communications | ||||||||||||
| Publisher: | Royal Society of Chemistry | ||||||||||||
| ISSN: | 1359-7345 | ||||||||||||
| Official Date: | 28 September 2019 | ||||||||||||
| Dates: |
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| Volume: | 55 | ||||||||||||
| Number: | 76 | ||||||||||||
| Page Range: | pp. 11446-11449 | ||||||||||||
| DOI: | 10.1039/C9CC05364F | ||||||||||||
| Status: | Peer Reviewed | ||||||||||||
| Publication Status: | Published | ||||||||||||
| Access rights to Published version: | Open Access (Creative Commons) | ||||||||||||
| Date of first compliant deposit: | 9 September 2019 | ||||||||||||
| Date of first compliant Open Access: | 9 September 2019 | ||||||||||||
| RIOXX Funder/Project Grant: |
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