Unexpected viability of pyridyl methanimine-based ligands for transition-metal-mediated living radical polymerization in aqueous media at ambient temperature
UNSPECIFIED (2001) Unexpected viability of pyridyl methanimine-based ligands for transition-metal-mediated living radical polymerization in aqueous media at ambient temperature. MACROMOLECULES, 34 (2). pp. 162-164. ISSN 0024-9297Full text not available from this repository.
Pyridylmethanimine-based ligands are used in aqueous media at neutral pH for the efficient living radical polymerization of hydrophilic monomers. High conversions (>90%), good molecular weight control, and low polydispersities (M-w/M-n < 1.20) were obtained for the polymerization of monomethoxy-capped oligo(ethylene glycol) methacrylate at 20 <degrees>C; faster rates, reduced control, and higher polydispersities were obtained at elevated temperatures.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||MACROMOLECULES|
|Publisher:||AMER CHEMICAL SOC|
|Date:||16 January 2001|
|Number of Pages:||3|
|Page Range:||pp. 162-164|
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