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Data for Methacrylate and Acrylate Diblock Copolymers via End-Capping using a combination of CCTP and FRP
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Haddleton, David M., Wemyss, Alan M., Efstathiou, Spyridon, Town, James S., Shegiwal, Ataulla, Whitfield, Richard, Atkins, Christophe J. and Patias, Georgios (2019) Data for Methacrylate and Acrylate Diblock Copolymers via End-Capping using a combination of CCTP and FRP. [Dataset]
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Abstract
Scalable methods of producing functional materials is of importance. Herein, we report the use of free radical copolymerisation of ω-unsaturated methacrylic macromonomers, as derived from catalytic chain transfer polymerisation (CCTP), with acrylic monomers in solution leading to block copolymers by varying the nature of the macromonomer. We demonstrate the effect that varying the molecular weight and ester side chain length of macromonomer from CCTP, has on the polymerisation leading to either graft or diblock copolymers. DOSY NMR, MALDI-ToF/ToF MS has allowed for the exploration of the extent to which varying the concentration of macromonomer has on the products formed. Importantly, during the successful synthesis of acrylic and methacrylic diblock copolymers with broad dispersities of each block, full consumption of the macromonomers was observed.
Item Type: | Dataset | ||||||||
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Divisions: | Faculty of Science > Chemistry | ||||||||
Type of Data: | Experimental data | ||||||||
Publisher: | Department of Chemistry | ||||||||
Official Date: | 13 November 2019 | ||||||||
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Date of first compliant deposit: | 4 March 2020 | ||||||||
Status: | Not Peer Reviewed | ||||||||
Publication Status: | Published | ||||||||
Access rights to Published version: | Open Access | ||||||||
Copyright Holders: | University of Warwick | ||||||||
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