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Fluorinated carboxylic acids as powerful building blocks for the formation of bimolecular monolayers
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Pinfold, Harry, Greenland, Christopher, Pattison, Graham and Costantini, Giovanni (2020) Fluorinated carboxylic acids as powerful building blocks for the formation of bimolecular monolayers. Chemical Communications, 56 (1). pp. 125-128. doi:10.1039/C9CC08361H ISSN 1359-7345.
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WRAP-fluorinated-carboxylic-acids-powerful-blocks-monolayers-Pinfold-2019.pdf - Accepted Version - Requires a PDF viewer. Download (2187Kb) | Preview |
Official URL: http://doi.org/10.1039/C9CC08361H
Abstract
We compare the ability of a prototypical dicarboxylic acid and its fluorinated analogue to act as molecular building blocks for the formation of self-assembled monolayers. Whilst fluorination is found to prevent homomolecular self-assembly, it greatly increases the ability of the carboxylic acid to act as a hydrogen bond donor for the formation of bimolecular networks.
Item Type: | Journal Article | ||||||||
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Subjects: | Q Science > QD Chemistry | ||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||
Library of Congress Subject Headings (LCSH): | Carboxylic acids , Monomolecular films | ||||||||
Journal or Publication Title: | Chemical Communications | ||||||||
Publisher: | Royal Society of Chemistry | ||||||||
ISSN: | 1359-7345 | ||||||||
Official Date: | 4 January 2020 | ||||||||
Dates: |
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Volume: | 56 | ||||||||
Number: | 1 | ||||||||
Page Range: | pp. 125-128 | ||||||||
DOI: | 10.1039/C9CC08361H | ||||||||
Status: | Peer Reviewed | ||||||||
Publication Status: | Published | ||||||||
Access rights to Published version: | Restricted or Subscription Access | ||||||||
Date of first compliant deposit: | 28 November 2019 | ||||||||
Date of first compliant Open Access: | 20 November 2020 |
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