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Data for UV irradiation of Cu-based complexes with aliphatic amine ligands as used in living radical polymerization

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Liarou, Evelina, Staniforth, Michael, Town, James, Marathianos, Arkadios, Grypioti, Maria, Li, Yongguang, Chang, Yujing, Efstathiou, Spyridon, Hancox, Ellis, Wemyss, Alan M., Wilson, Paul, Jones, Bryn, Aljuaid, Mohammed, Stavros, Vasilios G. and Haddleton, David M. (2019) Data for UV irradiation of Cu-based complexes with aliphatic amine ligands as used in living radical polymerization. [Dataset]

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Abstract

The effect UV irradiation on Cu(II)-based complexes with aliphatic amine ligands is investigated. Four aliphatic amines are used as ligands and Cu(II)Br2 as the metal source for the formation of catalyst complexes that can be used for the photoinduced Cu-RDRP of methyl acrylate. Different characterization techniques such as transient electronic absorption spectroscopy (TEAS), ultraviolet-visible (UV-Vis) spectroscopy, electrospray ionization time of flight mass spectrometry (ESI-ToF-MS) and cyclic voltammetry (CV) are applied in order to provide insights into the catalyst behaviour upon photo-irradiation. The excited-state dynamics, the electrochemical behaviour of the Cu(II)/Cu(I) redox couples and the detection of different species upon complexation of the ligand to the metal center (before and after UV irradiation) are further depicted in the quality of the obtained polymers.

Item Type: Dataset
Subjects: Q Science > QC Physics
Q Science > QP Physiology
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Type of Data: Experimental data
Library of Congress Subject Headings (LCSH): Ultraviolet radiation, Ultraviolet radiation -- Physiological effect, Polymerization, Photochemistry
Publisher: University of Warwick, Department of Chemistry
Official Date: 12 December 2019
Dates:
DateEvent
12 December 2019Published
3 December 2019Created
Status: Not Peer Reviewed
Publication Status: Published
Media of Output (format): .dat .txt .zip .bin .csv .xy .ami .baf .content .mcf .idx .method .result_c .xml .docx .collect .sample .temp .par .pdf .xwp .xml .dsw
Access rights to Published version: Open Access (Creative Commons)
Copyright Holders: University of Warwick
Description:

Experimental data presented in compressed (zipped) format containing 7 folders.

Folder Structure:
The files are organised by technique used for the characterisation of the final products.

Abbreviations:
NMR: Nuclear Magnetic Resonance
GPC: Gel permeation chromatography
ESI-ToF-MS: Electrospray Ionization-Time Of Flight (ESI-TOF) mass spectrometry (MS)
UV-Vis: Ultraviolet-Visible Spectroscopy
TEAS: Transient electronic absorption spectroscopy

Software used :
NMR : ACD labs
GPC: Agilent GPC/SEC software (version A.02.01).
ESI-ToF-MS: Bruker Analysis software
UV-Vis: Agilent Cary UV software, plot through Origin 8.0
TEAS: Labview was used to collect the data, Excel and Origin was used to manipulate/plot the data, Glotaran was used to fit the data.

Date of first compliant deposit: 12 December 2019
Date of first compliant Open Access: 12 December 2019
RIOXX Funder/Project Grant:
Project/Grant IDRIOXX Funder NameFunder ID
UNSPECIFIEDUniversity of Warwickhttp://dx.doi.org/10.13039/501100000741
EP/L015307/1[EPSRC] Engineering and Physical Sciences Research Councilhttp://dx.doi.org/10.13039/501100000266
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Contributors:
ContributionNameContributor ID
DepositorHaddleton, David M.35695

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