The Library
Identification of the cobalt(II) chloride 'mixed' solvate Co4Cl8(H2O)(4)(MeCN)(6): the ionic structure trans-[Co(H2O)(2)(MeCN)(4)] trans-[Co(H2O)(2)(MeCN)(2)(CoCl4)(2)]
Tools
Tools
Tools
UNSPECIFIED (2000) Identification of the cobalt(II) chloride 'mixed' solvate Co4Cl8(H2O)(4)(MeCN)(6): the ionic structure trans-[Co(H2O)(2)(MeCN)(4)] trans-[Co(H2O)(2)(MeCN)(2)(CoCl4)(2)]. TRANSITION METAL CHEMISTRY, 25 (5). pp. 534-536. ISSN 0340-4285
Full text not available from this repository.Abstract
The structure of the title compound features mononuclear octahedral Co-II cations, trans-[Co(H2O)(2)(MeCN)(4)](2+), and trinuclear anions, trans-[Co(H2O)(2)(MeCN)(2)(CoCl4)(2)](2-); the latter centrosymmetric units contain a central octahedral Co(H2O)(2)(MeCN)(2) moiety with two tetrahedral [CoCl4](2-) ligands. These two large ions are held in a network of intra- and inter-molecular hydrogen bonding.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | TRANSITION METAL CHEMISTRY |
| Publisher: | KLUWER ACADEMIC PUBL |
| ISSN: | 0340-4285 |
| Date: | October 2000 |
| Volume: | 25 |
| Number: | 5 |
| Number of Pages: | 3 |
| Page Range: | pp. 534-536 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/13192 |
Data sourced from Thomson Reuters' Web of Knowledge
Actions (login required)
 |
View Item |
