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From major to minor and back - a decisive assessment of C60H36 with respect to the Birch reduction of C-60

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UNSPECIFIED (2000) From major to minor and back - a decisive assessment of C60H36 with respect to the Birch reduction of C-60. CHEMICAL COMMUNICATIONS (14). pp. 1233-1234. ISSN 1359-7345

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Abstract

Hydrogenated fullerenes derived from the Birch reduction and from hydrogen transfer reduction of [60]fullerene have been examined by matrix-assisted laser desorption ionization; applying 9-nitroanthracene as the matrix, it has been possible to desorb and ionise the samples with such a low degree of fragmentation as to enable the establishment of the amount of hydrogen bound to the fullerene; in contrast to the currently assumed polyhydrofullerene distribution featuring C60H36 only as a minor component, evidence has been obtained which re-establishes C60H36 as the major product of the Birch reduction.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Journal or Publication Title: CHEMICAL COMMUNICATIONS
Publisher: ROYAL SOC CHEMISTRY
ISSN: 1359-7345
Date: 2000
Number: 14
Number of Pages: 2
Page Range: pp. 1233-1234
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/13244

Data sourced from Thomson Reuters' Web of Knowledge

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