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Crown ether complexation of Hg(II): Synthesis and crystal structure of [(HgCl2)(2)(dibenzo-24-crown-8)]
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UNSPECIFIED (2000) Crown ether complexation of Hg(II): Synthesis and crystal structure of [(HgCl2)(2)(dibenzo-24-crown-8)]. MAIN GROUP METAL CHEMISTRY, 23 (5). pp. 281-284. ISSN 0334-7575
Full text not available from this repository.Abstract
The dinuclear compound [(HgCl2)(2)(dibenzo-24-crown-8)] has been isolated as colourless, block crystals and structurally characterised by X-ray diffraction studies. The structure is centrosymmetric and consists of a core ClHg(mu-Cl)(2)HgCl unit entrapped within the ring cavity with each metal centre directly bonded to three of the crown oxygen atoms. Hg-Cl-terminal 2.306(4) Angstrom, Hg-Cl-bridging 2.326(4), 3.189(3) Angstrom and Hg-O-crown 2.640(9)- 2.772(8) Angstrom.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | MAIN GROUP METAL CHEMISTRY |
| Publisher: | FREUND PUBLISHING HOUSE LTD |
| ISSN: | 0334-7575 |
| Date: | May 2000 |
| Volume: | 23 |
| Number: | 5 |
| Number of Pages: | 4 |
| Page Range: | pp. 281-284 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/13336 |
Data sourced from Thomson Reuters' Web of Knowledge
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