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Data for Polymerisable surfactants for polymethacrylates using catalytic chain transfer polymerisation (CCTP) combined with sulfur free-RAFT in emulsion polymerisation
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Haddleton, David M., Shegiwal, Ataulla, Wemyss, Alan M., Liarou, Evelina, Town, James, Patias, Georgios, Marathianos, Arkadios, Efstathiou, Spyridon, Atkins, Christophe J. and Lester, Daniel (2020) Data for Polymerisable surfactants for polymethacrylates using catalytic chain transfer polymerisation (CCTP) combined with sulfur free-RAFT in emulsion polymerisation. [Dataset]
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OneDrive_1_11-06-2020.zip - Published Version Available under License Creative Commons Attribution 4.0. Download (150Mb) |
Abstract
Statistical copolymers of methacrylic acid and methyl methacrylate were synthesised via free radical catalytic chain transfer polymerisation (CCTP) in emulsion to form a hydrophilic emulsifier/surfactant. The vinyl-terminated oligomers were in turn utilised as chain transfer agents, with no further purification, for the formation of diblock copolymers with butyl and methyl methacrylate which constitutes the emulsifier via sulfur-free reversible addition–fragmentation chain transfer polymerisation (SF-RAFT). In turn these polymers were solubilized with various concentrations of ammonium hydroxide and utilised in the surfactant-free emulsion polymerization of butyl methacrylate using persulfate initiators, which also stabilized the polymer particles with observed no coagulation, with solid contents as high as 40%.
Item Type: | Dataset | ||||||||||||
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Subjects: | Q Science > QD Chemistry T Technology > TP Chemical technology |
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Divisions: | Faculty of Science > Chemistry | ||||||||||||
Type of Data: | Experimental data | ||||||||||||
Library of Congress Subject Headings (LCSH): | Polymerization, Surface active agents, Emulsion polymerization, Methacrylic acid | ||||||||||||
Publisher: | Department of Chemistry | ||||||||||||
Official Date: | 11 June 2020 | ||||||||||||
Dates: |
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Status: | Not Peer Reviewed | ||||||||||||
Publication Status: | Published | ||||||||||||
Media of Output: | .fid .xlsx | ||||||||||||
Access rights to Published version: | Open Access | ||||||||||||
Copyright Holders: | University of Warwick | ||||||||||||
Description: | Data record consists of a zip archive, organised according to sub-folders, and containing an accompanying readme file. |
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