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Determination of titanium NMR parameters of ATiO(3) compounds: correlations with structural distortion

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UNSPECIFIED (2000) Determination of titanium NMR parameters of ATiO(3) compounds: correlations with structural distortion. SOLID STATE NUCLEAR MAGNETIC RESONANCE, 15 (4). pp. 231-236. ISSN 0926-2040.

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Abstract

Solid state Ti-47,Ti-49 NMR spectra have been obtained for a number of pelovskite and ilmenite ATiO(3) compounds. The Ti-49 quadrupole coupling constant varies from 2.75 MHz (CaTiO3) to 15.5 MHz (MgTiO3) and the electric field gradient at the titanium site was found to correlate well with the shear strain, independent of structure. The chemical shift in the perovskite structures varies by similar to 160 ppm and correlates well with the mean Ti-O distance. The Mg-25 and Cd-113 NMR parameters are also reported for the relevant compounds. (C) 2000 Elsevier Science B.V. All rights reserved.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Q Science > QC Physics
Journal or Publication Title: SOLID STATE NUCLEAR MAGNETIC RESONANCE
Publisher: ELSEVIER SCIENCE BV
ISSN: 0926-2040
Official Date: April 2000
Dates:
DateEvent
April 2000UNSPECIFIED
Volume: 15
Number: 4
Number of Pages: 6
Page Range: pp. 231-236
Publication Status: Published

Data sourced from Thomson Reuters' Web of Knowledge

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