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Metal-free stabilization of monomeric antimony(I) : a carbene-supported stibinidene
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Dorsey, Christopher L., Mushinski, Ryan and Hudnall, Todd W. (2014) Metal-free stabilization of monomeric antimony(I) : a carbene-supported stibinidene. Chemistry - A European Journal, 20 (29). pp. 8914-8917. doi:10.1002/chem.201403578 ISSN 0947-6539.
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Official URL: http://dx.doi.org/10.1002/chem.201403578
Abstract
A diamidocarbene was coordinated to an antimony(III) dichloride Lewis acid. Subsequent reduction with magnesium gave a monomeric, formally antimony(I) fragment that is supported by the diamidocarbene. Spectroscopic, crystallographic, and computational analyses demonstrated that the carbene ligand engages the antimony(I) center in π‐backbonding resulting in a short (2.068(7) Å) SbC interaction that is comparable to those observed in known stibaalkenes.
Item Type: | Journal Article | ||||||
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Divisions: | Faculty of Science, Engineering and Medicine > Science > Life Sciences (2010- ) | ||||||
Journal or Publication Title: | Chemistry - A European Journal | ||||||
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||||
ISSN: | 0947-6539 | ||||||
Official Date: | July 2014 | ||||||
Dates: |
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Volume: | 20 | ||||||
Number: | 29 | ||||||
Page Range: | pp. 8914-8917 | ||||||
DOI: | 10.1002/chem.201403578 | ||||||
Status: | Peer Reviewed | ||||||
Publication Status: | Published | ||||||
Access rights to Published version: | Restricted or Subscription Access |
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