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The intercalation of 1,10-phenanthroline into layered NiPS3 via iron dopant seeding
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Ma, Xiaoping, Zhang, Lu, Xu, Chengchao, Dong, Qingxin, Walton, Richard I., Li, Zi-An, Shi, Honglong, Chen, Genfu, Hu, Jiangping, Li, Jianqi and Yang, Huaixin (2020) The intercalation of 1,10-phenanthroline into layered NiPS3 via iron dopant seeding. Chemical Communications, 56 (33). pp. 4603-4606. doi:10.1039/D0CC00636J ISSN 1359-7345.
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Official URL: http://dx.doi.org/10.1039/D0CC00636J
Abstract
Using 2% percent of iron dopants as reaction active sites yields a series of single crystals of 1,10-phenanthroline intercalated NiPS3, via solution reaction with aniline chloride, not possible by direct reaction. Experimental magnetic susceptibility measurements demonstrate that 1,10-phenanthroline intercalation suppresses the anti-ferromagnetism ordering at around 150 K in Fe0.02Ni0.98PS3, and gives rise to a ferrimagnetic phase transition at the temperature around 75 K. A intercalation mechanism is proposed for the reaction, and this dopant seeding method provides a new approach for intercalation into layered materials.
Item Type: | Journal Article | |||||||||||||||||||||||||||
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Subjects: | Q Science > QC Physics Q Science > QD Chemistry |
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Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | |||||||||||||||||||||||||||
Library of Congress Subject Headings (LCSH): | Antiferromagnetism, Ferrimagnetism, Transition metal compounds | |||||||||||||||||||||||||||
Journal or Publication Title: | Chemical Communications | |||||||||||||||||||||||||||
Publisher: | Royal Society of Chemistry | |||||||||||||||||||||||||||
ISSN: | 1359-7345 | |||||||||||||||||||||||||||
Official Date: | 28 April 2020 | |||||||||||||||||||||||||||
Dates: |
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Volume: | 56 | |||||||||||||||||||||||||||
Number: | 33 | |||||||||||||||||||||||||||
Page Range: | pp. 4603-4606 | |||||||||||||||||||||||||||
DOI: | 10.1039/D0CC00636J | |||||||||||||||||||||||||||
Status: | Peer Reviewed | |||||||||||||||||||||||||||
Publication Status: | Published | |||||||||||||||||||||||||||
Access rights to Published version: | Restricted or Subscription Access | |||||||||||||||||||||||||||
Date of first compliant deposit: | 19 March 2020 | |||||||||||||||||||||||||||
Date of first compliant Open Access: | 18 March 2021 | |||||||||||||||||||||||||||
RIOXX Funder/Project Grant: |
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