A structural study of methanethiolate adsorbed on Cu(100)
UNSPECIFIED. (2000) A structural study of methanethiolate adsorbed on Cu(100). JOURNAL OF PHYSICS-CONDENSED MATTER, 12 (10). pp. 2153-2161. ISSN 0953-8984Full text not available from this repository.
The interaction of methanethiol, CH3SH, with Cu(100) has been studied by S 1s photoemission, S K-edge near-edge x-ray absorption fine structure and normal-incidence standing x-ray wavefield absorption at both (200) and (111) reflections. The results indicate that a single methanethiolate species, CH3S-, is formed and this is bonded to the unreconstructed surface via the S atoms which adopt the fourfold symmetric hollow site. This conclusion confirms the results of a recent near-edge and surface extended x-ray absorption fine structure study, but contrasts with the established adsorbate-induced reconstruction produced by this species on Cu(111).
|Item Type:||Journal Article|
|Subjects:||Q Science > QC Physics|
|Journal or Publication Title:||JOURNAL OF PHYSICS-CONDENSED MATTER|
|Publisher:||IOP PUBLISHING LTD|
|Official Date:||13 March 2000|
|Number of Pages:||9|
|Page Range:||pp. 2153-2161|
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